ࡱ>   bjbj΀ 4^ ((kkkkk4GO%O%O%O%O%*&*&*&CCCCCCCUIKZCk*&*&*&*&*&CkkO%O%eGjCjCjC*&ZkO%kO%CjC*&CjCjCjCO%0[P*vjCC{G0GjCQL?pQLjCQLkjC@*&*&jC*&*&*&*&*&CCjC*&*&*&G*&*&*&*&QL*&*&*&*&*&*&*&*&*&( 1: NADP (BETA-) CAS # 53598 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: PHOSPHORUSHAZARDOUS POLYMERIZATION WIL The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAFION CAS # 118473680 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation of fumes from overheating material may cause polymer fume fever, a flu-like illness with fever, chills and cough. It occurs several hours after exposure and subsides within 24 hours even in the absence of treatment. Polymer fume fever does not cause permanent injury and the effects are not cumulative. ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation of fumes from overheating material may cause polymer fume fever, a flu-like illness with fever, chills and cough. It occurs several hours after exposure and subsides within 24 hours even in the absence of treatment. Polymer fume fever does not cause permanent injury and the effects are not cumulative. ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation of fumes from overheating material may cause polymer fume fever, a flu-like illness with fever, chills and cough. It occurs several hours after exposure and subsides within 24 hours even in the absence of treatment. Polymer fume fever does not cause permanent injury and the effects are not cumulative. ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation of fumes from overheating material may cause polymer fume fever, a flu-like illness with fever, chills and cough. It occurs several hours after exposure and subsides within 24 hours even in the absence of treatment. Polymer fume fever does not cause permanent injury and the effects are not cumulative. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAFION 1035 PERFLUORINATED CAS # 31175209 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation of fumes from overheating material may cause polymer fume fever, a flu-like illness with fever, chills and cough. It occurs several hours after exposure and subsides within 24 hours even in the absence of treatment. Polymer fume fever does not cause permanent injury and the effects are not cumulative. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NALIDIXIC ACID CAS # 389082 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2040.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Causes photosensitiveity. Exposure to light can result in allergic reactions resulting in dermatologic lesions, which can vary from sunburnlike responses to edematous, vesiculated lesions, or bullae Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Blood. Eyes. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE May cause hyperglycemia, exacerbation of epilepsy, and photosensitive reactions of the skin and eyes. Possible skin reactions may include hyperpigmentation, swelling, redness, and blistering. Possible eye changes may include keratoconjunctivitis or corneal and lens opacities. Exposure can cause: Nausea, dizziness, and headache. Stomach pains, vomiting, diarrhea. Drowsiness. Confusion. Weakness. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42/43 Risk Statements: May cause sensitization by inhalation and skin contact. S: 22-36/37-45 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NALIDIXIC ACID SODIUM CAS # 3374058 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Causes photosensitiveity. Exposure to light can result in allergic reactions resulting in dermatologic lesions, which can vary from sunburnlike responses to edematous, vesiculated lesions, or bullae Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Reproductive system. Nerves. Liver. Kidneys. Heart. SIGNS AND SYMPTOMS OF EXPOSURE May cause hyperglycemia, exacerbation of epilepsy, and photosensitive reactions of the skin and eyes. Possible skin reactions may include hyperpigmentation, swelling, redness, and blistering. Possible eye changes may include keratoconjunctivitis or corneal and lens opacities. Exposure can cause: Nausea, dizziness, and headache. Stomach pains, vomiting, diarrhea. Drowsiness. Confusion. Weakness. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents, Reducing agents, Strong bases, Alkali metals, Ammonia, Peroxides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42/43 Risk Statements: May cause sensitization by inhalation and skin contact. S: 22 36/37 45 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NALOXONE CAS # 51481608 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 22 24/25 26 36/37/39 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHA CAS # 803036 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C . . . . . . . . . NO NFPA CODE ASSIGNED EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 2 - LD50 mg/Kg INHALATION RISK INDEX <1 - LC50 3400.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xn N Indication of Danger: Highly Flammable. Harmful. Dangerous for the environment. R: 11 38 50/53 65 67 Risk Statements: Highly flammable. Irritating to skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Vapors may cause drowsiness and dizziness. S: 16 60 61 62 Safety Statements: Keep away from sources of ignition - no smoking. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHA CAS # 8032324 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . H . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 13461.2 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xn N Indication of Danger: Highly Flammable. Harmful. Dangerous for the environment. R: 11 38 50/53 65 67 Risk Statements: Highly flammable. Irritating to skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Vapors may cause drowsiness and dizziness. S: 16 60 61 62 Safety Statements: Keep away from sources of ignition - no smoking. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 300 ppm OSHA Short Term Exposure Limit 400 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 300 ppm Immediately Dangerous to Life and Health 1000 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 300 ppm DOE Short Term Exposure Limit 300 ppm DOE Ceiling Limit 395 ppm Immediately Dangerous to Life and Health 395 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALALDEHYDIC ACID (1,8-) CAS # 5811870 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALDEHYDE (1-) CAS # 66773 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 667.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 230 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. REACTIVE PROPERTIES HANDLING: Avoid prolonged or repeated exposure. Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALDEHYDE (2-) CAS # 66999 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALENE CAS # 91203 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . H I J K L NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 5 - LD50 490.0 mg/Kg NEUROTOXIC - RISK INDEX 4.0 INHALATION RISK INDEX <1 - LC50 340.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Eyes. Blood. Kidneys. Lungs. Central nervous system. Liver. Heart. SIGNS AND SYMPTOMS OF EXPOSURE Gastrointestinal disturbances. Nausea, headache, and vomiting. Exposure can cause: Naphthalene is retinotoxic and systemic absorption of its vapors above 15ppm, may result in cataracts, optical neuritis, injuries to the cornea, and marked eye irritation. Ingestion of large quantities have been reported to cause severe hemolytic anemia and hemoglobinuria. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Coma. Seizures. Exposure can cause renal failure. Anemia. Convulsions. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .0200 mm Hg @ 20 C FLASH POINT 176 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: For small (incipient) fires, use media such as"alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn-N Indication of Danger: Harmful. Dangerous for the environment. R: 22-40-50/53 Risk Statements: Harmful if swallowed. Limited evidence of a carcinogenic effect. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 36/37-46-60-61 Safety Statements: Wear suitable protective clothing and gloves. If swallowed, seek medical advice immediately and show this container or label. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 10 ppm OSHA Short Term Exposure Limit 15 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 10 ppm ACGIH Short Term Exposure Limit 15 ppm Immediately Dangerous to Life and Health 250 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 ppm DOE Short Term Exposure Limit 15 ppm DOE Ceiling Limit 35 ppm Immediately Dangerous to Life and Health 250 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALENE BORONIC ACID (1-) CAS # 13922413 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Boron oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALENE SULFONAMIDE (2-) CAS # 1576472 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3800.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 24/25 22 Safety Statements: Avoid contact with skin and eyes. Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALENE SULFONIC ACID (ALPHA, 1-) CAS # 130143 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALENEACETAMIDE (ALPHA-) CAS # 86862 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1690.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 41 Risk Statements: Harmful if swallowed. Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALENEDISULFONIC ACID (1,5-) CAS # 1655294 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALENEDISULFONIC ACID (2,6-) CAS # 1655454 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALENEMETHYLAMINE (1-) CAS # 118310 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes irritation. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 230 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents, Chloroformates. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Store in a cool dry place. Store under nitrogen. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALENESULFONYL CHLORIDE (1-) CAS # 85461 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALENESULFONYL CHLORIDE (2-) CAS # 93118 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHALYL HYDROXYLAMINE SODIUM (N,N,1,8-) CAS # 6207892 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHAQUINONE (1,2-) CAS # 524425 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.8 - LD50 75.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHIONIC ACID (1,4-) CAS # 84866 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 7500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES StorageHANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOHYDROQUINONE (ALPHA,PARA-) CAS # 571608 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1800.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 37/38 41 Risk Statements: Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOIC ACID (1-) CAS # 86555 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 7645.2 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOIC ACID (2-) CAS # 93094 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOL (1-) CAS # 90153 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 5 - LD50 1870.0 mg/Kg INHALATION RISK INDEX 1.3 - LC50 420.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Eyes. Liver. Kidneys. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .340 mm Hg @ 20 C FLASH POINT 257 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. SPECIAL REQUIREMENTS Store under inert gas. Air and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 21/22-37/38-41 Risk Statements: Harmful in contact with skin and if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 22-26-37/39 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25 mg/m3 DOE Short Term Exposure Limit 75 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOL (2-) CAS # 135193 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 4 - LD50 1960.0 mg/Kg INHALATION RISK INDEX 1.7 - LC50 770.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Damage to the eyes. SIGNS AND SYMPTOMS OF EXPOSURE Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE 1.4 mm Hg @ 20 C FLASH POINT 307.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 20/22 50 Risk Statements: Harmful by inhalation and if swallowed. Very toxic to aquatic organisms. S: 24/25 61 Safety Statements: Avoid contact with skin and eyes. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0025 mg/m3 DOE Short Term Exposure Limit .0075 mg/m3 DOE Ceiling Limit .05 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOL AS CAS # 92773 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOL BLUE BLACK CAS # 1064488 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOL DISULFONIC ACID DISODIUM CAS # 20349397 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: IDE SULFUR OXIDES The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOL GREEN B CAS # 19381501 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOLBENZEIN (ALPHA-) CAS # 145506 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOLDISULFONIC ACID DIPOTASSIUM (6,8-) CAS # 842182 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37 Risk Statements: Irritating to eyes and respiratory system. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOLDISULFONIC ACID DISODIUM CAS # 135513 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOLPHTHALEIN CAS # 596010 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Causes eye and skin irritation. May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOLSULFONIC ACID SODIUM (1:4-) CAS # 6099576 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 S PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOQUINONE (1,4-) CAS # 130154 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E F G . . J K L NFPA HAZARD CODES (H,F,R,O) 4 0 0 ACUTE TOXICTY RISK INDEX 5 - LD50 190.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 46.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be fatal if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Blood. Liver. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 25 26 36/37/38 43 50 Risk Statements: Toxic if swallowed. Very toxic by inhalation. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. Very toxic to aquatic organisms. S: 26 36/37 45 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .075 mg/m3 DOE Short Term Exposure Limit .25 mg/m3 DOE Ceiling Limit 1.5 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOSULTONE CAS # 83318 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 38 Risk Statements: Irritating to skin. S: 22 28 Safety Statements: Do not breathe dust. After contact with skin, wash immediately with plenty of water. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOXYACETIC ACID (2-) CAS # 120230 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 600.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials to Avoid: O FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOYL CHLORIDE (1-) CAS # 879185 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 230 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 37 Risk Statements: Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHOYL CHLORIDE (2-) CAS # 2243836 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES User Exposure: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYL ACETATE (1-) CAS # 830819 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Bases, Strong oxidizing agents, Strong FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYL ACETATE (2-) CAS # 1523111 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Acids, Bases, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep container closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. STORAGE: Keep container closed\. Store at 2-8%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYL ISOCYANATE (1-) CAS # 86840 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: CARBON DIOXIDE. DRY CHEMICAL POWDER. TOXIC EMISSIONS WHEN BURNED: EHAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCT REACTIVE PROPERTIES BASE-CATALYZED REACTIONS OF ISOCYANATES WITH ALCOHOLS SHOULD BE CARRIED OUTIN INERT SOLVENTS. IN THE ABSENCE OF SUCH SOLVENTS THE REACTIONS OFTEN OCCURWITH EXPLOSIVE VIOLENCE.BASE-CATALYZED REACTIONS OF ISOCYANATES WITH ALCOHOLSSHOULD BE CARRIED OUT IN INERT SOLVENTS. IN THE ABSENCE OF SUCH SOLVENTS THEREACTIONS OFTEN OCCUR WITH EXPLOSIVE VIOLENCE. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYL ISOTHIOCYANATE (1-) CAS # 551064 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . J K L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 200.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Lachrymator. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Water, Alcohols, Strong bases, Amines, Acids, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides Sulfur oxides Store at 2-8C Keep tightly closed. Store under nitrogen. Moisture sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store under nitrogen. Store at 2-8%C SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 20/21 25 36/37/38 42 Risk Statements: Harmful by inhalation and in contact with skin. Toxic if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation. S: 22 26 36/37 45 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYL PHOSPHATE DISODIUM SALT (1-) CAS # 2183177 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam\. Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits t REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYL PHOSPHATE MONOSODIUM (1-) CAS # 1136896 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYL PHOSPHATE MONOSODIUM (1-) CAS # 81012897 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYLACETIC ACID (1-) CAS # 86873 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam\. Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits t REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. Indication of Danger: Harmful. Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. SARA LISTED: No TSCA INVENTORY ITEM: Yes CANADA REGULATORY INFORMATION accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR. DSL: No Section 1 - Product and Company Information Product Number T4791 Brand SIGMA Section 2 - Composition/Information on Ingredient Substance Name CAS # SARA 313 TUNGSTOSILICIC ACID 12027-38-2 No Formula H4O40SiW12 Section 3 - Hazards Identification Irritant. Irritating to eyes, respiratory system and skin. HMIS RATING HEALTH: 2 REACTIVITY: 0 NFPA RATING HEALTH: 2 REACTIVITY: 0 For additional information on toxicity, please refer to Section 11. Section 4 - First Aid Measures ORAL EXPOSURE conscious. Call a physician. INHALATION EXPOSURE If inhaled, remove to fresh air. If not breathing give DERMAL EXPOSURE In case of contact, immediately wash skin with soap and copious amounts of water. EYE EXPOSURE In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. FLASH POINT N/A AUTOIGNITION TEMP FLAMMABILITY N/A Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTING and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits toxic fumes under fire conditions. Section 6 - Accidental Release Measures Wear respirator, chemical safety goggles, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP raising dust. Ventilate area and wash spill site after material pickup is complete. Section 7 - Handling and Storage HANDLING User Exposure: Do not breathe dust. Avoid contact with eyes, STORAGE Suitable: Keep tightly closed. Section 8 - Exposure Controls / PPE ENGINEERING CONTROLS Safety shower and eye bath. Mechanical exhaust required. PERSONAL PROTECTIVE EQUIPMENT Respiratory: Government approved respirator. Hand: Compatible chemical-resistant gloves. Eye: Chemical safety goggles. Wash thoroughly after handling. Section 9 - Physical/Chemical Properties Property Value At Temperature or Pressure Molecular Weight 2,878 AMU BP/BP Range N/A MP/MP Range N/A Freezing Point N/A Vapor Pressure N/A Saturated Vapor Conc. N/A SG/Density N/A Bulk Density N/A Odor Threshold N/A Volatile% N/A Water Content N/A Solvent Content N/A Evaporation Rate N/A Viscosity N/A Partition Coefficient N/A Decomposition Temp. N/A Flash Point N/A Explosion Limits N/A Flammability N/A Autoignition Temp N/A Refractive Index N/A Miscellaneous Data N/A Solubility N/A Section 10 - Stability and Reactivity STABILITY Stable: Stable. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Silicon oxide. HAZARDOUS POLYMERIZATION Section 11 - Toxicological Information ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and Section 12 - Ecological Information No data available. APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an environmental regulations. Section 14 - Transport Information DOT Proper Shipping Name: None Non-Hazardous for Transport: This substance is IATA Non-Hazardous for Air Transport: Non-hazardous for air Section 15 - Regulatory Information EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYLAMINE (BETA-) CAS # 91598 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 727.0 mg/Kg INHALATION RISK INDEX <1 - LC50 cancer suspect agent ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bladder. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 45 22 51/53 Risk Statements: May cause cancer. Also harmful if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 45 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 35 mg/m3 Immediately Dangerous to Life and Health 300 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYLETHYLENEDIAMINE CAS # 1465254 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYLPHTHALAMIC ACID (N,1-) CAS # 132661 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 8200.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPHTHYLUREA CAS # 6950841 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: ON MONOXIDENITROGEN OXIDES The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NAPROXEN SODIUM CAS # 26159342 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause gastro-intestinal disturbances, headache, dizziness, nervousness, skin rash, itching, tinnitus, oedema, depression, drowsiness, insomnia, and blurred vision. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NARINGIN CAS # 10236472 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEOCUPROINE HYDROCHLORIDE CAS # 7296200 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEODYMIUM CAS # 7440008 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Rare earth compounds may cause delayed blood clotting leading to hemorrhages. Inhalation of rare earths may cause sensitiveity to heat, itching, and increased awareness of odor and taste. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Nitrogen, Strong oxidizing agents, Phosphorous acid, Halogens, Strong acids. FIRE EXTINGUISHER: Use approved class D extinguishers or smother with drysand, dry ground limestone, or dry clay. Do not use water. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F-Xi Indication of Danger: Highly Flammable. Irritant. R: 11-36/37/38 Risk Statements: Highly flammable. Irritating to eyes, respiratory system and skin. S: 16-26-33-36/37/39 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take precautionary measures against static discharges. Wear suitable protective clothing, gloves, and eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0008 mg/m3 DOE Short Term Exposure Limit .0025 mg/m3 DOE Ceiling Limit .02 mg/m3 Immediately Dangerous to Life and Health .1 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEOMYCIN SULFATE CAS # 1405103 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 1.1 - LD50 36129.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. Ears. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and Aminoglycosides are associated with significant nephrotoxicity and/or ototoxicity. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Nitrogen oxides Store at 2-8C REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42/43 Risk Statements: May cause sensitization by inhalation and skin contact. S: 22-36/37-45 Safety Statements: Do not breathe dust. Wear suitable protective seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEON CAS # 7440019 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Can cause rapid suffocation. SIGNS AND SYMPTOMS OF EXPOSURE May be harmful. Exposure can cause: Nausea, headache, and vomiting. CONDITIONS AGGRAVATED BY EXPOSURE At high concentrations neon functions as a simple asphyxiant by displacing air. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Gas VAPOR PRESSURE** mm Hg @ 20 C SEGREGATION: SHELF # 3 STORAGE GROUP(S): i - CorrosiveorNon-Toxic Gas WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Use water spray or fog nozzle to keep cylinder cool. Move cylinder away from fire if there is no risk. REACTIVE PROPERTIES HANDLING: Do not breathe gas. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Cylinder temperature should not exceed 125%F (52%C)\. SPECIAL REQUIREMENTS Contents under pressure. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 38 Safety Statements: In case of insufficient ventilation, wear suitable respiratory equipment. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 65000 ppm DOE Short Term Exposure Limit 65000 ppm DOE Ceiling Limit 230000 ppm Immediately Dangerous to Life and Health 400000 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEOPENTYL ALCOHOL CAS # 75843 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 3 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable FLASH POINT 82.4 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 10 36/37 Risk Statements: Flammable. Irritating to eyes and respiratory system. S: 16 26 36/37 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEOPENTYL CHLOROFORMATE CAS # 20412388 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 3 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Toxic if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 33.6 mm Hg @ 20 C FLASH POINT 89.6 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Amines, Alcohols, Strong bases, Acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Phosgene gasHydrogen chloride gas Store at 2-8C Vent periodically. May develop pressure. Open carefully. Keep container closed. Keep away from heat, sparks, and open flame. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. Store at 2-8%C SPECIAL REQUIREMENTS Vent periodically. May develop pressure. Open carefully. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23-34-10 Risk Statements: Toxic by inhalation. Causes burns. Flammable. S: 16-26-36/37/39-45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEOPENTYL GLYCOL ADIPATE CAS # 27925071 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Foam and water spray are effective but may cause frothing. REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEOPENTYL GLYCOL DIACRYLATE CAS # 2223827 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5190.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Free radical initiators. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Limit storage time. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 24 36/38 43 Risk Statements: Toxic in contact with skin. Irritating to eyes and skin. May cause sensitization by skin contact. S: 28 39 45 Safety Statements: After contact with skin, wash immediately with plenty of soap-suds. Wear eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEOPENTYL GLYCOL PROPOXYLATE DIACRYLATE CAS # 84170741 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 0 1 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.5 - LD50 15.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. Brain. Bladder. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation studies on toluene have demonstrated the development of inflammatory and ulcerous lesions of the penis, prepuce, and scrotum in animals. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Amines, Acids, Bases, Free radical initiators. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES User Exposure: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 43 Risk Statements: Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEOPENTYL GLYCOL SEBACATE CAS # 28759548 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEOPTERIN (D-) CAS # 2009645 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEUTRAL RED CAS # 553242 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NEW COCCINE CAS # 2611827 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 8000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NIACINAMIDE CAS # 98920 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Eyes. Liver. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Other symptoms of exposure can include anorexia, excessive salivation, pupillary constriction, bronchoconstriction, respiratory failure, tightness of the chest, coma, pulmonary, ureter, and bladder effects. CONDITIONS AGGRAVATED BY EXPOSURE May produce reversible liver damage PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .000420 mm Hg @ 20 C FLASH POINT 302 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL CAS # 7440020 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . B . . E . . . . J . L NFPA HAZARD CODES (H,F,R,O) 2 4 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 5.3 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergi reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Lungs. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Oxidizing agents, Sulfur. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 40 43 Risk Statements: Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. S: 22 36 Safety Statements: Do not breathe dust. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1 mg/m3 DOE Short Term Exposure Limit 4.5 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL BISCYCLOPENTADIENE CAS # 1271289 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 3 - LD50 490.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Handle and store under inert gas. Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F T Indication of Danger: Highly Flammable. Toxic. R: 49 11 22 43 Risk Statements: May cause cancer by inhalation. Highly flammable. Harmful if swallowed. May cause sensitization by skin contact. S: 53 36/37/39 45 Safety Statements: Avoid exposure - obtain special instructions before use. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL BORIDE CAS # 12007011 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. May cause irritation. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong bases. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides Borane/boron oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 20/21/22 42/43 Risk Statements: May cause cancer. Harmful by inhalation, in contact with skin and if swallowed. May cause sensitization by inhalation and skin contact. S: 53 26 36/37/39 45 Safety Statements: Avoid exposure - obtain special instructions before use. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL BORIDE HYDRATE CAS # 207569117 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. May cause irritation. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong bases. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides Borane/boron oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Moisture sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL CARBONATE HYDROXYDIDE CAS # 39380740 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1300.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Blood. Cardiovascular system. Immune system. Testes. Skin. Lungs. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Gastrointestinal disturbances. Lung irritation. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Dermatitis. Exposure can cause: PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn-N Indication of Danger: Harmful. Dangerous for the environment. R: 22-40-43-50/53 Risk Statements: Harmful if swallowed. Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 22-36/37-60-61 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL SULFATE CAS # 7786814 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 REPRODUCTIVE RISK INDEX 5.3 ACUTE TOXICTY RISK INDEX 3.3 - LD50 264.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn-N Indication of Danger: Harmful. Dangerous for the environment. R: 22-40-42/43-50/53 Risk Statements: Harmful if swallowed. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact. Very toxic to aquatic organisms, may caus long-term adverse effects in the aquatic environment. S: 22-36/37-60-61 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 10 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2.64 mg/m3 DOE Short Term Exposure Limit 2.64 mg/m3 DOE Ceiling Limit 2.64 mg/m3 Immediately Dangerous to Life and Health 26.4 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL SULFATE HEXAHYDRATE CAS # 10101970 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 2 0 0 REPRODUCTIVE RISK INDEX 5.3 ACUTE TOXICTY RISK INDEX 3.3 - LD50 264.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn-N Indication of Danger: Harmful. Dangerous for the environment. R: 22-40-42/43-50/53 Risk Statements: Harmful if swallowed. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 22-36/37-60-61 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 10 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4.48 mg/m3 DOE Short Term Exposure Limit 4.48 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 44.8 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) ACETATE TETRAHYDRATE CAS # 6018899 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.3 - LD50 350.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Causes dermatitis. Respiratory: May cause allergic respiratory reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 22 43 Risk Statements: May cause cancer. Also harmful if swallowed. May cause sensitization by skin contact. S: 53 36/37 45 Safety Statements: Avoid exposure - obtain special instructions before use. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4.24 mg/m3 DOE Short Term Exposure Limit 4.24 mg/m3 DOE Ceiling Limit 4.24 mg/m3 Immediately Dangerous to Life and Health 42.4 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) ACETYLACETONATE CAS # 3264822 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE May liberate 2,4-pentanedione upon decomposition. 2,4-Pentanedione has the following toxicological hazards: toxic, irritant, neurological hazard, teratogen, possible mutagen, target organ - thymus. In humans, 2,4-pentanedione is reported to cause contact dermatitis and contact urticaria. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid all contact. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 49 22 43 Risk Statements: May cause cancer by inhalation. Harmful if swallowed. May cause sensitization by skin contact. S: 53 36/37/39 45 Safety Statements: Avoid exposure - obtain special instructions before use. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) BROMIDE CAS # 13462889 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Causes dermatitis. Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T-N Indication of Danger: Toxic. Dangerous for the environment. R: 45-22-43-50/53 Risk Statements: May cause cancer. Harmful if swallowed. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53-36/37-45-60-61 Safety Statements: Avoid exposure - obtain special instructions before use. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 10 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 3.72 mg/m3 DOE Short Term Exposure Limit 3.72 mg/m3 DOE Ceiling Limit 3.72 mg/m3 Immediately Dangerous to Life and Health 37.2 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) CARBONATE CAS # 3333673 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 REPRODUCTIVE RISK INDEX 5.3 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: UNUSUAL FIRE AND EXPLOSIONS HAZARDS HAZARDOUS POLYMERIZATION WILL NOT OCCUR. ADDITIONAL INFORMATION NONCOMBUSTIBLE. REACTIVE PROPERTIES EXPLOSION OCCURRED WHEN SODIUM CARBONATE WAS APPLIED TO RED HOT ALUMINUM. INTHE PRESENCE OF FLUORINE, CARBONATES DECOMPOSE AT ORDINARY TEMPERATURES WITHINCANDESCENCE. EXPLOSIVE WHEN MIXED WITH MAGNESIUM. WHEN A MIXTURE OFAMORPHOUS SILICON AND AN ALKALI CARBONATE IS HEATED, A VIGOROUS REACTION,ATTENDED BY INCANDESCENCE, OCCURS. Immediately Dangerous to Life and Health 10 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2.02 mg/m3 DOE Short Term Exposure Limit 2.02 mg/m3 DOE Ceiling Limit 2.02 mg/m3 Immediately Dangerous to Life and Health 20.2 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) CHLORIDE CAS # 7718549 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . B . . . . . . . J . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 5.3 ACUTE TOXICTY RISK INDEX 3.7 - LD50 105.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Gastrointestinal disturbances. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Peroxides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Immediately Dangerous to Life and Health 10 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2.21 mg/m3 DOE Short Term Exposure Limit 2.21 mg/m3 DOE Ceiling Limit 2.21 mg/m3 Immediately Dangerous to Life and Health 22.1 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) CHLORIDE HEXAHYDRATE CAS # 7791200 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 186.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.4 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. SENSITIZATION Sensitization: Causes dermatitis. Sensitization: Will occur TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Gastrointestinal disturbances. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Peroxides. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 45 25 36/38 43 50/53 Risk Statements: May cause cancer. Toxic if swallowed. Irritating to eyes and skin. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 36/37 45 60 61 Safety Statements: Avoid exposure - obtain special instructions before use. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 10 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4.05 mg/m3 DOE Short Term Exposure Limit 4.05 mg/m3 DOE Ceiling Limit 40.5 mg/m3 Immediately Dangerous to Life and Health 40.5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) FLUORIDE CAS # 10028189 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 1 REPRODUCTIVE RISK INDEX 5.3 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Blood. Skin. Cardiovascular system. Immune system. Testes. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of fluoride overexposure may include salivation, nausea, vomiting, abdominal pain, fever, and labored breathing. Fluoride ion can reduce serum calcium levels possibly causing fatal hypocalcemia. Prolonged exposure to fluoride dusts, vapors, or mists results in perforation of the nasal septum. Chronic effects include excessive calcification of the bones, ligaments, and tendons. Dermatitis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Exposure can cause: Gastrointestinal disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Peroxides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 36/37/38 42/43 Risk Statements: May cause cancer. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. S: 53 26 36/37/39 45 Safety Statements: Avoid exposure - obtain special instructions before use. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 10 mg/m The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) IODIDE CAS # 13462903 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Lungs. Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Iodine Hydrogen iodide Nickel/nickel oxides REACTIVE PROPERTIES HANDLIN User Exposure: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 61 42/43 Risk Statements: May cause cancer. May cause harm to the unborn child. May cause sensitization by inhalation and skin contact. S: 53 22 26 36/37/39 45 Safety Statements: Avoid exposure - obtain special instructions before use. Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) NITRATE HEXAHYDRATE CAS # 13138459 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 2 OX INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Explosive Oxidizing Agent SEGREGATION: SHELF # 3 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide k - Explosive/Unstable WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Organic materials, Finely powdered metals, Strong reducing agents, Acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 3.11 mg/m3 DOE Short Term Exposure Limit 3.11 mg/m3 DOE Ceiling Limit 12.5 mg/m3 Immediately Dangerous to Life and Health 31.1 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) NITRATE HEXAHYDRATE CAS # 13478007 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 1 0 2 OX ACUTE TOXICTY RISK INDEX 2.5 - LD50 1620.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. skin contact can cause itching, which may be followed by erythema and nodular erruption on the web of the fingers, and on the wrists and forearms. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Explosive Oxidizing Agent SEGREGATION: SHELF # 3 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide k - Explosive/Unstable WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Organic materials, Finely powdered metals, Strong reducing agents, Acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O T Indication of Danger: Oxidizing. Toxic. R: 45 8 22 43 Risk Statements: May cause cancer. Contact with combustible material may cause fire. Also harmful if swallowed. May cause sensitization by skin contact. S: 53 17 36/37 45 Safety Statements: Avoid exposure - obtain special instructions before use. Keep away from combustible material. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 10 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4.96 mg/m3 DOE Short Term Exposure Limit 4.96 mg/m3 DOE Ceiling Limit 49.6 mg/m3 Immediately Dangerous to Life and Health 49.6 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) OXIDE CAS # 1313991 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E F G . . J K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Lungs. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 49 43 53 Risk Statements: May cause cancer by inhalation. May cause sensitization by skin contact. May cause long-term adverse effects in the aquatic environment. S: 53 61 45 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. Avoid release to the environment. Refer to special instructions/safety data sheets. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 10 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.27 mg/m3 DOE Short Term Exposure Limit 1.27 mg/m3 DOE Ceiling Limit 12.7 mg/m3 Immediately Dangerous to Life and Health 12.7 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) PERCHLORATE HEXAHYDRATE CAS # 13520611 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX REPRODUCTIVE RISK INDEX 5.3 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Ammonia, Organic materials, Amines, Strong acids, Reducing agents, Alcohols. FIRE EXTINGUISHER: Dry chemical powder. TOXIC EMISSIONS WHEN BURNED: Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid all contact. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O T Indication of Danger: Oxidizing. Toxic. R: 49 8 36/38 43 Risk Statements: May cause cancer by inhalation. Contact with combustible material may cause fire. Irritating to eyes and skin. May cause sensitization by skin contact. S: 53 16 26 36/37/39 45 Safety Statements: Avoid exposure - obtain special instructions before use. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protectiv clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) PHTHALOCYANINE TETRASULFONIC ACID NA CAS # 27835990 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Nickel/nickel oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 49 42/43 Risk Statements: May cause cancer by inhalation. May cause sensitization by inhalation and skin contact. S: 53 22 36/37/39 45 Safety Statements: Avoid exposure - obtain special instructions before use. Do not breathe dust. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICKEL(II) TETRAFLUOROBORATE CAS # 14708146 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 REPRODUCTIVE RISK INDEX 5.3 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. Lungs. Eyes. Skin. Bones. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Symptoms of fluoride overexposure may include salivation, nausea, vomiting, abdominal pain, fever, and labored breathing. Fluoride ion can reduce serum calcium levels possibly causing fatal hypocalcemia. Prolonged exposure to fluoride dusts, vapors, or mists results in perforation of the nasal septum. Chronic effects include excessive calcification of the bones, ligaments, and tendons. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Strong oxidizing agents, Bases, Metals. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Nickel/nickel oxides Boron oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 31 34 42/43 Risk Statements: May cause cancer. Contact with acids liberates toxic gas. Causes burns. May cause sensitization by inhalation and skin contact. S: 53 23 26 36/37/39 45 Safety Statements: Avoid exposure - obtain special instructions before use. Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICOTINAMIDE ADENINE DINUCLEOTIDE CAS # 53849 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICOTINAMIDE ADENINE DINUCLEOTIDE (BETA-) CAS # 606688 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Phosphorous oxides Store at 2-8C Keep tightly closed. Store in a cool dry place. Store Light sensitive. Hygroscopic. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store with desiccant. Store at 2-8%C SPECIAL REQUIREMENTS Light sensitive. Hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICOTINAMIDE ADENINE DINUCLEOTIDE PHOSPHATE (BETA- CAS # 2646711 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Liver. Heart. SIGNS AND SYMPTOMS OF EXPOSURE Can cause CNS depression. Exposure can cause: Nausea, headache, and vomiting. Narcotic effect. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Phosphorous oxides Store at 2-8C Keep tightly closed. Store with desiccant. Light sensitive. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store with desiccant. Store at 2-8%C SPECIAL REQUIREMENTS Light sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICOTINE CAS # 22083745 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . B C . E . . . I J . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 8.3 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4 - LD50 50.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX 1.7 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be fatal if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Peripheral nervous system. Central nervous system. Skeletal muscle. G.I. System. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Stomach pains, vomiting, diarrhea. Convulsions. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE Causes cyanosis. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .0300 mm Hg @ 20 C FLASH POINT 213.8 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under argon\. SPECIAL REQUIREMENTS Store under inert gas. Hygroscopic. Air and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 25 27 51/53 Risk Statements: Toxic if swallowed. Very toxic in contact with skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 36/37 45 61 Safety Statements: Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 5 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.29 mg/m3 DOE Short Term Exposure Limit 3.5 mg/m3 DOE Ceiling Limit 3.5 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICOTINE CAS # 54115 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . B C . E . . . I J . . NFPA HAZARD CODES (H,F,R,O) 4 1 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 8.3 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4 - LD50 50.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX 1.7 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be fatal if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Peripheral nervous system. Central nervous system. Skeletal muscle. G.I. System. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Stomach pains, vomiting, diarrhea. Convulsions. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE Causes cyanosis. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .0300 mm Hg @ 20 C FLASH POINT 213.8 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under argon\. SPECIAL REQUIREMENTS Store under inert gas. Hygroscopic. Air and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 25 27 51/53 Risk Statements: Toxic if swallowed. Very toxic in contact with skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 36/37 45 61 Safety Statements: Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 5 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 3.5 mg/m3 Immediately Dangerous to Life and Health 5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICOTINE HEMISULFATE CAS # 65305 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C D E . . . I J K . NFPA HAZARD CODES (H,F,R,O) 3 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5 - LD50 50.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Readily absorbed through skin. Toxic if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: May be fatal if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Skeletal muscle. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Extreme nausea, vomiting, evacuation of bowel and bladder, mental confusion, twitching, convulsions. Exposure can cause: PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .0000100 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. Do not breathe vapor. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 24/25-26-36/37/38-63 Risk Statements: Toxic in contact with skin and if swallowed. Very toxic by inhalation. Irritating to eyes, respiratory system and skin. Possible risk of harm to the unborn child. S: 26-36/37/39-28-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. After contact with skin, wash immediately with plenty of soap and water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4 mg/m3 DOE Short Term Exposure Limit 9 mg/m3 DOE Ceiling Limit 9 mg/m3 Immediately Dangerous to Life and Health 9 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICOTINIC ACID CAS # 59676 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Overexposure to nicotinic acid can produce a powerful peripheral vasodilating action. This effect is seen as an intense flushing of the skin and occurs about 15 to 60 minutes after exposure. It is accompanied by a sense of warmth, tingling, and itching of the skin and subsides gradually over a period of 15 to 30 minutes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE May produce reversible liver damage PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 379.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .75 mg/m3 DOE Short Term Exposure Limit 2 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICOTINIC ACID OXIDE (N-) CAS # 2398814 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NICOTINOYL CHLORIDE HYDROCHLORIDE CAS # 20260531 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NIFEDIPINE CAS # 21829254 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1022.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Cardiovascular system. Blood. Eyes. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of overexposure include dizziness or light-headedness, peripheral edema, nausea, weakness, headache, and flushing. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NIGROSIN CAS # 8005036 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24 Safety Statements: Do not breathe dust. Avoid contact with skin. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NILE BLUE CAS # 3625578 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Causes eye and skin irritation. May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: appropriate foam. REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NILE BLUE CHLORIDE CAS # 2381853 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NILE RED CAS # 7385673 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NINHYDRIN CAS # 485472 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store SPECIAL REQUIREMENTS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .3 mg/m3 DOE Short Term Exposure Limit 1 mg/m3 DOE Ceiling Limit 6 mg/m3 Immediately Dangerous to Life and Health 35 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NIOBIUM CAS # 7440031 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 2 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently in air SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Strong bases, Strong oxidizing agents, Halogens, Oxygen. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 17 Risk Statements: Spontaneously flammable in air. S: 17 Safety Statements: Keep away from combustible material. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 40 mg/m3 DOE Short Term Exposure Limit 125 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NIOBIUM(V) CHLORIDE CAS # 10026127 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1400.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Store at 2-8C Keep tightly closed. Store in a cool dry place. Store under nitrogen. Moisture sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. Store at 2-8%C SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 20/21/22 Risk Statements: Causes burns. Harmful by inhalation, in contact with skin and if swallowed. S: 26 28 27 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NIPECOTIC ACID CAS # 498953 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NISOLDIPINE CAS # 63675729 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1257.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. May cause irritation. TARGET ORGAN(S) OR SYSTEM(S) Cardiovascular system. SIGNS AND SYMPTOMS OF EXPOSURE May cause flushing, headache, nausea, dizziness, systemic blood pressure, and vascular resistance reduction. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C REACTIVE PROPERTIES STORAGE Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITRIC ACID CAS # 7697372 HAZARDOUS CHEMICAL OF CONCERN DEPARTMENT OF HOMELAND SECURITY CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . H . . . . NFPA HAZARD CODES (H,F,R,O) 4 0 1 OX ACUTE TOXICTY RISK INDEX 2.3 - LD50 2345.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Metals. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. Quench with large quantities of water. Use water spray to cool fire-exposed containers. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: O C Indication of Danger: Oxidizing. Corrosive. R: 8 35 Risk Statements: Contact with combustible material may cause fire. Causes severe burns. S: 23 26 36 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 25 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .53 ppm DOE Short Term Exposure Limit .53 ppm DOE Ceiling Limit 24 ppm Immediately Dangerous to Life and Health 92 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITRILOTRIACETIC ACID CAS # 139139 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1100.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bladder. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 212 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong bases, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36-40 Risk Statements: Harmful if swallowed. Irritating to eyes. Limited evidence of a carcinogenic effect. S: 26-36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 35 mg/m3 DOE Short Term Exposure Limit 100 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITRILOTRIACETIC ACID CAS # 5064313 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1100.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bladder. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 212 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong bases, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36-40 Risk Statements: Harmful if swallowed. Irritating to eyes. Limited evidence of a carcinogenic effect. S: 26-36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITRILOTRIACETIC ACID DISODIUM CAS # 15467206 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1460.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bladder. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid all contact. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 40 Risk Statements: Harmful if swallowed. Limited evidence of a carcinogenic effect. S: 36 Safety Statements: Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITRO BLUE TETRAZOLIUM CHLORIDE CAS # 298839 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. Suitable: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITRO OXINDOLE (5:2-) CAS # 20870795 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4100.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Section 4 - First Aid Measures ORAL EXPOSURE If swallowed, wash out mouth with water provided person is conscious. Call a physician. INHALATION EXPOSURE If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. DERMAL EXPOSURE In case of contact, immediately wash skin with soap and copious amounts of water. EYE EXPOSURE In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. Section 5 - Fire Fighting Measures FLASH POINT N/A AUTOIGNITION TEMP N/A FLAMMABILITY N/A EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTING Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits toxic fumes under fire conditions. Section 6 - Accidental Release Measures PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear respirator, chemical safety goggles, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete. Section 7 - Handling and Storage HANDLING User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Suitable: Keep tightly closed. Section 8 - Exposure Controls / PPE ENGINEERING CONTROLS Safety shower and eye bath. Mechanical exhaust required. PERSONAL PROTECTIVE EQUIPMENT Respiratory: Government approved respirator. Hand: Compatible chemical-resistant gloves. Eye: Chemical safety goggles. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Section 9 - Physical/Chemical Properties Appearance Physical State: Solid Property Value At Temperature or Pressure Molecular Weight 178.15 AMU pH N/A BP/BP Range N/A MP/MP Range 233 - 236 C Freezing Point N/A Vapor Pressure N/A Vapor Density N/A Saturated Vapor Conc. N/A SG/Density N/A Bulk Density N/A Odor Threshold N/A Volatile% N/A VOC Content N/A Water Content N/A Solvent Content N/A Evaporation Rate N/A Viscosity N/A Surface Tension N/A Partition Coefficient Log Kow: 0.537 Decomposition Temp. N/A Flash Point N/A Explosion Limits N/A Flammability N/A Autoignition Temp N/A Refractive Index N/A Optical Rotation N/A Miscellaneous Data N/A Solubility N/A N/A = not available Section 10 - Stability and Reactivity STABILITY Stable: Stable. Materials to Avoid: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Nitrogen oxides. HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occur Section 11 - Toxicological Information ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. Sensitization: Strong sensitizer. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITRO TYROSINE (3-) CAS # 621443 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROACETOPHENONE (2'-) CAS # 577593 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1600.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 233.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid prolonged or repeated exposure. Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROACETOPHENONE (3'-) CAS # 121891 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3250.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAG Suitable: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROACETOPHENONE (4'-) CAS # 100196 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROANILINE (2-) CAS # 88744 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 3 - LD50 1600.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 2529.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Readily absorbed through skin. Toxic if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Toxic if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Heart. Lungs. Liver. Blood. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .002400 mm Hg @ 20 C FLASH POINT 332.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25-33-52/53 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 28-36/37-45-61 Safety Statements: After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROANILINE (3-) CAS # 99092 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 3 - LD50 535.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Toxic if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Heart. Kidneys. Liver. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .000800 mm Hg @ 20 C FLASH POINT 384.8 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 33 52/53 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 28 36/37 45 61 Safety Statements: After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .6 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 12.5 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROANILINE (4-) CAS # 100016 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 3 1 1 ACUTE TOXICTY RISK INDEX 2.8 - LD50 750.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Toxic if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Heart. Lungs. Liver. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Exposure to and/or consumption of alcohol may increase toxic effects. Exposure can cause: Headache. Unconsciousness. Coughing, chest pains, difficulty in breathing. Drowsiness. Nausea. Cyanosis. Ataxia. Diarrhea. Vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. p-Nitroaniline is readily absorbed by inhalation, ingestion, or skin absorption. It is a strong methemoglobin former. Cyanosis is the first manifestation of toxicity. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 415.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents, Strong reducing agents, Plastics, Rubber. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 33 52/53 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 28 36/37 45 61 Safety Statements: After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 300 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 9 mg/m3 DOE Ceiling Limit 300 mg/m3 Immediately Dangerous to Life and Health 300 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROANISIDINE (PARA,2-) CAS # 96968 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 14100.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be fatal if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be fatal if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be fatal if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 26/27/28 33 52/53 Risk Statements: Very toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 28 36/37 45 61 Safety Statements: After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROANISOLE (3-) CAS # 555033 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2300.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Causes eye and skin irritation. May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 24/25 Safety Statements: Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROANISOLE (4-) CAS # 100174 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 1 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2300.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 266 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong bases, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION R: 52/53 Risk Statements: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 61 Safety Statements: Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROANTHRACENE (9-) CAS # 602608 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IARC CARCINOGEN LIST Rating: Group 3 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROARGININE (N,OMEGA-L-) CAS # 2149704 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid all contact. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZALDEHYDE (2-) CAS # 552896 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1935.5 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .009600 mm Hg @ 20 C FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZALDEHYDE (3-) CAS # 996016 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1034.5 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZALDEHYDE (3-) CAS # 99616 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZALDEHYDE (4-) CAS # 555168 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3200.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. Sensitization: Strong sensitizer. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Narcotic effect. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 36 40 43 68 Risk Statements: Irritating to eyes. Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. Possible risk of irreversible effects. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZALDEHYDE OXIME (4-) CAS # 1129379 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E F G . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 180.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong reducing agents, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES User Exposure: Do not breathe dust. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZAMIDE (3-) CAS # 645090 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 476.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZAMIDE (4-) CAS # 619807 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 476.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. S: 27 28 36/37/39 45 Safety Statements: Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZENE CAS # 98953 HAZARDOUS CHEMICAL OF CONCERN DEPARTMENT OF HOMELAND SECURITY CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX A . . D E . . . . . K . NFPA HAZARD CODES (H,F,R,O) 3 2 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.3 - TD50 25.5 mg/Kg ACUTE TOXICTY RISK INDEX 4 - LD50 349.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 1.6 - LC50 2000.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Spleen. Liver. Male reproductive system. Central nervous system. Blood. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Exposure to and/or consumption of alcohol may increase toxic effects. Exposure can cause: CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .150 mm Hg @ 20 C FLASH POINT 190.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T-N Indication of Danger: Toxic. Dangerous for the environment. R: 23/24/25-40-48/23/24-51/53-62 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of impaired fertility. S: 28-36/37-45-61 Safety Statements: After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 1 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 1 ppm Immediately Dangerous to Life and Health 200 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1 ppm DOE Short Term Exposure Limit 3 ppm DOE Ceiling Limit 19.9 ppm Immediately Dangerous to Life and Health 200 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZENESULFONAMIDE (4-) CAS # 6325935 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZENESULFONYL CHLORIDE (2-) CAS # 1694924 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 W ACUTE TOXICTY RISK INDEX 2.4 - LD50 1720.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZENESULFONYL CHLORIDE (3-) CAS # 121517 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZENESULFONYL CHLORIDE (4-) CAS # 98748 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Strong bases, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZIMIDAZOLE (5,6-) CAS # 94520 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZIMIDAZOLINONE (5:2-) CAS # 93845 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZOIC ACID (2-) CAS # 552169 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1960.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZOIC ACID (3-) CAS # 121926 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4677.4 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37 Risk Statements: Harmful if swallowed. Irritating to eyes and respiratory system. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZOIC ACID (4-) CAS # 62237 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1960.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Damage to the eyes. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 458.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 41 Risk Statements: Harmful if swallowed. Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZONITRILE (3-) CAS # 619249 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 476.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/22 Risk Statements: Harmful by inhalation and if swallowed. S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZONITRILE (4-) CAS # 619727 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C D E . . . I J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.2 - LD50 30.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Toxic if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZOYL AZIDE (PARA-) CAS # 2733417 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 3 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if inhaled or swallowed. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Many azides cause a fall in blood pressure and some inhibit enzyme action. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Explosive Shock sensitive Explosive SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Strong oxidizing agents, Acids, Avoid contact with metal salts. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xn Indication of Danger: Highly Flammable. Harmful. R: 2 11 20/22 36/37/38 Risk Statements: Risk of explosion by shock, friction, fire, or other sources of ignition. Highly flammable. Harmful by inhalation and if swallowed. Irritating to eyes, respiratory system and skin. S: 7/9 16 26 33 Safety Statements: Keep container tightly closed and in well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take precautionary measures against static discharges. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZOYL CHLORIDE (2-) CAS # 610140 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 2 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible Explosive FLASH POINT 235 F SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Strong bases. FIRE EXTINGUISHER: Water spray. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 5 34 Risk Statements: Heating may cause an explosion. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZOYL CHLORIDE (3-) CAS # 121904 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 1 W ACUTE TOXICTY RISK INDEX 2.3 - LD50 2460.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 230 F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Water, Alcohols, Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Do not use water. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 5 21 34 37 Risk Statements: Heating may cause an explosion. Harmful in contact with skin. Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZOYL CHLORIDE (4-) CAS # 122043 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 1 W ACUTE TOXICTY RISK INDEX 2.4 - LD50 1809.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 215.6 F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Do not use water. Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits toxic TOXIC EMISSIONS WHEN BURNED: Tin/tin oxidesROUTE OF EXPOSURE REACTIVE PROPERTIES HANDLING and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZYL ALCOHOL (2-) CAS # 612259 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Use protective clothing, gloves, and mask. Avoid contact and inhalation. STORAGE: Keep container closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZYL ALCOHOL (4-) CAS # 619738 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Use protective clothing, gloves, and mask. Avoid contact and inhalation. STORAGE: Keep container closed. Store in a cool dry place GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZYL BROMIDE (2-) CAS # 3958609 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 230 F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Oxidizing agents, Amines, Bases, Alcohols. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas and nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZYL BROMIDE (4-) CAS # 100118 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Alcohols, Bases, Amines, Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZYL CHLORIDE (2-) CAS # 612237 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if inhaled or swallowed. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 233.6 F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Bases, Alcohols, Amines, Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZYL CHLORIDE (3-) CAS # 619238 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if inhaled or swallowed. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 230 F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Bases, Alcohols, Amines, Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZYL CHLORIDE (4-) CAS # 100141 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 W ACUTE TOXICTY RISK INDEX 2.4 - LD50 1809.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .0500 mm Hg @ 20 C Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Bases, Alcohols, Amines, Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 Risk Statements: Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 28 mg/m3 Immediately Dangerous to Life and Health 125 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZYL PYRIDINE (4,4-) CAS # 1083483 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZYLAMINE HYDROCHLORIDE (3-) CAS # 26177435 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROBENZYLAMINE HYDROCHLORIDE (4-) CAS # 18600425 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROCATECHOL (4-) CAS # 3316094 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Lungs. Exposure may cause: Damage to the lungs. Repeated exposure may cause asthma. Nausea, dizziness, and headache. Lung irritation. To the best of our knowledge, the chemical, physical, and PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesROUTE OF EXPOSURE REACTIVE PROPERTIES HANDLING skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROCINNAMALDEHYDE (2-) CAS # 1466882 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed\. Store at 2-8C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROCINNAMALDEHYDE (TRANS-) CAS # 1734798 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed\. Store at 2-8C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROCINNAMIC ACID (2-) CAS # 612419 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROCINNAMIC ACID (3-) CAS # 555680 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROCINNAMIC ACID (4-) CAS # 619896 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROCINNAMOYL CHLORIDE (TRANS,4-) CAS # 61921333 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To th best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROETHANE CAS # 79243 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1100.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.7 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Liver. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Damage to the liver. Damage to the kidneys. Exposure can cause: Nausea, dizziness, and headache. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 15.6 mm Hg @ 20 C FLASH POINT 87 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Oxidizing agents, Strong oxidizing agents, Strong reducing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 10 20/22 Risk Statements: May cause cancer. Flammable. Harmful by inhalation and if swallowed. S: 53 9 23 41 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. Keep container in a well-ventilated place. Do not breathe fumes. In case of fire and/or explosion do not breathe fumes. Immediately Dangerous to Life and Health 1000 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 100 ppm DOE Short Term Exposure Limit 100 ppm DOE Ceiling Limit 200 ppm Immediately Dangerous to Life and Health 1000 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROETHANOL (2-) CAS # 625489 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROFURALDEHYDE (5:2-) CAS # 698635 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 91.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 16 Safety Statements: Keep away from sources of ignition - no smoking. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROFURANTOIN CAS # 67209 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . I J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 604.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Liver. Nerves. Blood. Lungs. Kidneys. Reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, oappropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 42/43 Risk Statements: Harmful if swallowed. May cause sensitization by inhalation and skin contact. S: 22 36/37 45 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROGEN CAS # 7727379 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Can cause rapid suffocation. SIGNS AND SYMPTOMS OF EXPOSURE Nausea, headache, and vomiting. May be harmful. Exposure can cause: CONDITIONS AGGRAVATED BY EXPOSURE At high concentrations nitrogen functions as a simple asphyxiant by displacing air. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Gas VAPOR PRESSURE** mm Hg @ 20 C SEGREGATION: SHELF # 3 STORAGE GROUP(S): i - CorrosiveorNon-Toxic Gas WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use water spray or fog nozzle to keep cylinder cool. Move cylinder away from fire if there is no risk. REACTIVE PROPERTIES HANDLING: Do not breathe gas. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Cylinder temperature should not exceed 125%F (52%C)\. SPECIAL REQUIREMENTS Contents under pressure. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 38 Safety Statements: In case of insufficient ventilation, wear suitable respiratory equipment. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 65000 ppm DOE Short Term Exposure Limit 65000 ppm DOE Ceiling Limit 230000 ppm Immediately Dangerous to Life and Health 400000 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROINDAZOLE (5-) CAS # 5401945 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: XIDENITROGEN OXIDES The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROINDOLE (5-) CAS # 614960 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, headache, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROINDOLE (7-) CAS # 6960425 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROISATIN (5-) CAS # 611096 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 40 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. S: 7 22 36/37/39 45 Safety Statements: Keep container tightly closed. Do not breathe dust. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROMETHANE CAS # 75525 HAZARDOUS CHEMICAL OF CONCERN DEPARTMENT OF HOMELAND SECURITY CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX A . . D . . . . I . K . NFPA HAZARD CODES (H,F,R,O) 1 3 2 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.1 - TD50 40.4 mg/Kg ACUTE TOXICTY RISK INDEX 2.7 - LD50 940.0 mg/Kg NEUROTOXIC - RISK INDEX 2.0 INHALATION HAZARD INHALATION RISK INDEX 2.9 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable Explosive VAPOR PRESSURE 27.3 mm Hg @ 20 C FLASH POINT 96.8 F SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Amines, Strong acids, Strong bases, Strong oxidizing agents, Strong reducing agents Copper, Copper alloys. FIRE EXTINGUISHER: Carbon dioxide. Do not use dry chemical powder extinguisher on this material. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 5 10 22 Risk Statements: Heating may cause an explosion. Flammable. Harmful if swallowed. S: 41 Safety Statements: In case of fire and/or explosion do not breathe fumes. Immediately Dangerous to Life and Health 750 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 20 ppm DOE Short Term Exposure Limit 60 ppm DOE Ceiling Limit 750 ppm Immediately Dangerous to Life and Health 750 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITRON CAS # 2218942 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITRONAPHTHALENE (1-) CAS # 86577 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 120.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 327.2 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F T N Indication of Danger: Highly Flammable. Toxic. Dangerous for the environment. R: 11 25 51/53 Risk Statements: Highly flammable. Toxic if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 16 45 60 61 Safety Statements: Keep away from sources of ignition - no smoking. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITRONAPHTHALENE (2-) CAS # 581895 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: ARBON MONOXIDENITROGEN OXIDE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITRONIUM TETRAFLUOROBORATE CAS # 13826863 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . G . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen fluoride Boron oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Handle and store under argon\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 42/43 Risk Statements: Causes burns. May cause sensitization by inhalation and skin contact. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4.37 mg/m3 DOE Short Term Exposure Limit 13.1 mg/m3 DOE Ceiling Limit 21.8 mg/m3 Immediately Dangerous to Life and Health 150 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENACYL BROMIDE (3-) CAS # 2227647 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE Causes sneezing. Do not inhale. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENANTHROLINE HYDRATE (5,1,10-) CAS # 4199886 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENOL (2-) CAS # 88755 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 334.0 mg/Kg INHALATION RISK INDEX 1.9 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Prolonged contact can cause: Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .410 mm Hg @ 20 C FLASH POINT 215.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 52/53 Risk Statements: Harmful if swallowed. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.25 mg/m3 DOE Short Term Exposure Limit 4 mg/m3 DOE Ceiling Limit 30 mg/m3 Immediately Dangerous to Life and Health 150 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENOL (3-) CAS # 554847 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 328.0 mg/Kg INHALATION RISK INDEX 1.5 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .1000 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 41 38 Risk Statements: Harmful if swallowed. Risk of serious damage to eyes. Irritating to skin. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.25 mg/m3 DOE Short Term Exposure Limit 4 mg/m3 DOE Ceiling Limit 30 mg/m3 Immediately Dangerous to Life and Health 150 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENOL (4-) CAS # 100027 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . I J K . NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 202.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX 1.6 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Central nervous system. Eyes. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Damage to the eyes. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .1000 mm Hg @ 20 C FLASH POINT 336.2 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 33 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. S: 28 Safety Statements: After contact with skin, wash immediately with plenty of polyethylene glycol. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .75 mg/m3 DOE Short Term Exposure Limit 2.5 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL ACETATE (4-) CAS # 830035 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES STORAGE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL BORONIC ACID (2-) CAS # 5570194 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Boron oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL CHLOROFORMATE (2-) CAS # 50353009 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at 2-8C Keep tightly closed. Vent periodically. May develop pressure. Open carefully. Moisture sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. Open carefully. STORAGE: Keep tightly closed. Store at 2-8%C SPECIAL REQUIREMENTS Vent periodically. May develop pressure. Open carefully. Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 34 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Causes burns. S: 26 27 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL CHLOROFORMATE (4-) CAS # 7693461 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong bases, Acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at 2-8C Keep tightly closed. May develop pressure. Open carefully. Moisture sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. Open carefully. STORAGE: Keep tightly closed. Store at 2-8%C SPECIAL REQUIREMENTS May develop pressure. Open carefully. Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 36/37 Risk Statements: Causes burns. Irritating to eyes and respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL DISULFIDE (3-) CAS # 537917 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL DISULFIDE (4-) CAS # 100323 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 40 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. S: 36 Safety Statements: Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL FORMATE (4-) CAS # 1865016 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 S PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: When heated to decomposition it may emit: HAZARDOUS EXOTHERMIC REACTIONS Hazardous Exothermic Reactions: Will not occur Store at 2-8C REACTIVE PROPERTIES STORAGE Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 23 24/25 Safety Statements: Do not breathe vapor. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL FURFURAL (5,2-) CAS # 20000968 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL GALACTOPYRANOSIDE CAS # 369073 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL GALACTOPYRANOSIDE (PARA:B,D-) CAS # 3150241 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store at -20%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL HYDRAZINE (2-) CAS # 3034193 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 2 INHALATION RISK INDEX <1 - LC50 skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Exposure can cause: Blood effects. Anemia. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Explosive SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or TOXIC EMISSIONS WHEN BURNED: oxide and nitrogen oxides HAZARDOUS POLYMERIZATION Hazardous Polymeri Store at 2-8C Keep container closed. Keep away from heat, sparks, REACTIVE PROPERTIES HANDLING Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL ISOTHIOCYANATE (4-) CAS # 2131615 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxidesSulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 36/37/38 42 Risk Statements: Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL PHOSPHATE (PARA-) CAS # 4264839 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Light sensitive. Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 24/25 22 Safety Statements: Avoid contact with skin and eyes. Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL PHOSPHATE BISCYCLOHEXYLAMINE (4-) CAS # 14545825 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYL THIOUREA (1,4:2-) CAS # 3696228 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLACETIC ACID (4-) CAS # 104030 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 1 ACUTE TOXICTY RISK INDEX 3 - LD50 500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLACETIC ACID (META-) CAS # 1877732 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, onskin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLACETONITRILE (4-) CAS # 555215 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Strong bases, Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep container closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 14 22 Safety Statements: Keep away from acids. Do not breathe dust. Immediately Dangerous to Life and Health 25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLALANINE (PARA-) CAS # 2922409 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 124.9 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLALANINE MONOHYDRATE (PARA-) CAS # 949995 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: IDE NITROGEN OXIDES The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLAZO RESORCINOL (4,4-) CAS # 74395 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 300.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLAZONAPHTHOL (4,4,1-) CAS # 5290620 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, andclothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 22 24/25 26 36 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLBUTYRIC ACID (4:4-) CAS # 5600624 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLENEDIAMINE (4,1,2-) CAS # 99569 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 681.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. Multiple Routes: Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong reducing agents, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 43 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLETHYL BROMIDE (2,4-) CAS # 5339264 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 43 Risk Statements: Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLGLUCOPYRANOSIDE (2-) CAS # 2816242 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C REACTIVE PROPERTIES STORAGE Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLGLUCOPYRANOSIDE (4-) CAS # 2492877 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Eyes. Kidneys. Liver. Heart. SIGNS AND SYMPTOMS OF EXPOSURE Gastrointestinal disturbances. May cause convulsions. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Alkali metals, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTIN Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Store in a cool dry place\. Incompatible Materials: Acids Acid chlorides Acid anhydrides Oxidizing agents Reducing agents Alkali metals GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/22 36/38 Risk Statements: Harmful by inhalation and if swallowed. Irritating to eyes and skin. S: 7 24 45 Safety Statements: Keep container tightly closed. Avoid contact with skin. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLGUANIDINOBENZOATE HYDROCHLORIDE (PARA-) CAS # 19135172 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE Potent inhibitor of sperm acrosin (an enzyme with an essential function in the fertilization process) prevents fertilization in a number of animal species. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATIO Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLHYDRAZINE (4-) CAS # 100163 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 2 ACUTE TOXICTY RISK INDEX 2.8 - LD50 816.7 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. May cause disorders of the blood which can include cyanosis, anemia, and red cell destruction. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Explosive SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xn Indication of Danger: Highly Flammable. Harmful R: 5 11 22 36/37/38 43 Risk Statements: Heating may cause an explosion. Highly flammable. Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 16 26 36/37/39 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHENYLSULFENYL ALANINE CAS # 7675469 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 S PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: Store at -20C REACTIVE PROPERTIES STORAGE Store at -20%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHTHALIC ACID (3-) CAS # 603112 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 41 Risk Statements: Irritating to eyes, respiratory system and skin. Risk of serious damage to eyes. S: 26 36/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHTHALIC ACID (4-) CAS # 610275 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHTHALIC ANHYDRIDE (3-) CAS # 641703 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPHTHALIMIDE (4-) CAS # 89407 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes on skin,on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPIPERONYL ALCOHOL (6-) CAS # 15341089 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPROPANE (1-) CAS # 108032 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 3 - LD50 455.0 mg/Kg NEUROTOXIC - RISK INDEX 2.0 INHALATION HAZARD INHALATION RISK INDEX 2.8 - LC50 *** ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Damage to the liver. Damage to the kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Damage to the liver. Damage to the kidneys. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 7.5 mm Hg @ 20 C FLASH POINT 95 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 10 20/21/22 Risk Statements: Flammable. Harmful by inhalation, in contact with skin and if swallowed. S: 9 Safety Statements: Keep container in a well-ventilated place. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 25 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 25 ppm Immediately Dangerous to Life and Health 1000 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25 ppm DOE Short Term Exposure Limit 25 ppm DOE Ceiling Limit 25 ppm Immediately Dangerous to Life and Health 1000 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPROPANE (2-) CAS # 79469 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 3 - LD50 720.0 mg/Kg NEUROTOXIC - RISK INDEX 2.0 INHALATION HAZARD INHALATION RISK INDEX 2.8 - LC50 3100.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. TARGET ORGAN(S) OR SYSTEM(S) Liver. Blood. Damage to the liver. SIGNS AND SYMPTOMS OF EXPOSURE Warning: overexposure may cause serious liver disorders. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Damage to the liver. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 13.0 mm Hg @ 20 C FLASH POINT 78.8 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Copper. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure.STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 10 20/2 Risk Statements: May cause cancer. Flammable. Also harmful by inhalation and if swallowed. S: 53 45 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 10 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 10 ppm Immediately Dangerous to Life and Health 100 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25 ppm DOE Short Term Exposure Limit 30 ppm DOE Ceiling Limit 50 ppm Immediately Dangerous to Life and Health 100 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROPROPANOL (2:1-) CAS # 2902967 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 213.8 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 23 24/25 Safety Statements: Do not breathe vapor. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROQUINOLINE (5-) CAS # 607341 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 40 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. S: 7 22 36 45 Safety Statements: Keep container tightly closed. Do not breathe dust. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROSALICYLIC ACID (5-) CAS # 96979 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROSOBENZENE CAS # 586969 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.9 - LD50 57.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.2 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .150 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 20/21 25 Risk Statements: Harmful by inhalation and in contact with skin. Toxic if swallowed. S: 26 36/37 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROSODIMETHYLANILINE (4-) CAS # 138896 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 3.9 - LD50 65.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Readily absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong reducing agents, Acetic acid, Acetic anhydride. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F T Indication of Danger: Highly Flammable. Toxic. R: 11 25 36/37/38 43 Risk Statements: Highly flammable. Toxic if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 16 26 36/37 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROSODIPHENYLAMINE (4-) CAS # 156105 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Damage to the liver. Damage to the kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Exposure can cause: Damage to the liver. Damage to the kidneys. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/38 Risk Statements: Harmful if swallowed. Irritating to eyes and skin. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .1 mg/m3 DOE Short Term Exposure Limit .3 mg/m3 DOE Ceiling Limit 2 mg/m3 Immediately Dangerous to Life and Health 150 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROSONAPHTHOL (1:2-) CAS # 131919 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROSONAPHTHOL (2,1-) CAS # 132536 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROSTYRENE (3-) CAS # 586390 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 225 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROSTYRENE (BETA-) CAS # 102965 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 1 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. TARGET ORGAN(S) OR SYSTEM(S) Brain. Liver. Kidneys. Bladder. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation studies on toluene have demonstrated the development of inflammatory and ulcerous lesions of the penis, prepuce, and scrotum in animals. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Lung irritation, chest pain, and edema which may be fatal. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable FLASH POINT 48 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Store under nitrogen. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROSTYRENE (TRANS,BETA-) CAS # 5153673 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Store at 2-8C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROSULFONAZO III CAS # 1964892 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROTOLUENE (2-) CAS # 88722 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 3 1 3 ACUTE TOXICTY RISK INDEX 5 - LD50 891.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 101.7 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. TARGET ORGAN(S) OR SYSTEM(S) Male reproductive system. Female reproductive system. Kidneys. Spleen. Liver. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobi which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible Explosive VAPOR PRESSURE .0152 mm Hg @ 20 C FLASH POINT 203 F Shock sensitive Explosive SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 23/24/25 33 51/53 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 28 37 45 61 Safety Statements: After contact with skin, wash immediately with plenty of soap-suds. Wear suitable gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 2 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 2 ppm Immediately Dangerous to Life and Health 200 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 6 ppm DOE Ceiling Limit 50 ppm Immediately Dangerous to Life and Health 60 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROTOLUENE (4-) CAS # 99990 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 3 OX ACUTE TOXICTY RISK INDEX 5 - LD50 1960.0 mg/Kg INHALATION RISK INDEX <1 - LC50 129.9 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Toxic if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) skin. Cardiovascular system. G.I. System. Central nervous system. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Explosive VAPOR PRESSURE .0378 mm Hg @ 20 C Shock sensitive Explosive Oxidizing Agent SEGREGATION: SHELF # 3 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Strong bases, Reducing agents, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi Indication of Danger: Oxidizing. Irritant. R: 8 36/37/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. S: 17 26 36/37/39 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 2 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 2 ppm Immediately Dangerous to Life and Health 200 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 6 ppm DOE Ceiling Limit 10 ppm Immediately Dangerous to Life and Health 200 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROTOLUENE (META-) CAS # 99081 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 3 ACUTE TOXICTY RISK INDEX 5 - LD50 1072.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 1.2 - LC50 131.8 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible Explosive VAPOR PRESSURE .147 mm Hg @ 20 C FLASH POINT 215.6 F Shock sensitive Explosive SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Oxidizing agents, Reducing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Indication of Danger: Toxic. R: 23/24/25 33 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. S: 36/37 45 Safety Statements: Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 2 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 2 ppm Immediately Dangerous to Life and Health 200 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 6 ppm DOE Ceiling Limit 50 ppm Immediately Dangerous to Life and Health 200 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NITROURACIL (5-) CAS # 611085 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10483.9 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NIVALENOL CAS # 23282204 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.4 - LD50 19.5 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Vesicant. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Exposure can cause: Nausea, vomiting, diarrhea. Hemorrhage. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES STORAGE Store at 2-8%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONACHLOR (TRANS-) CAS # 39765805 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX A . . . . . . . . . K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 4.7 - TD50 1.0 mg/Kg ACUTE TOXICTY RISK INDEX 3 - LD50 500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONACOSANE CAS # 630035 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONADECANONE (2-) CAS # 629663 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 212 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONAFLUOROBUTANE SULFONYL FLUORIDE CAS # 375724 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONANOIC ACID CAS # 112050 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .1000 mm Hg @ 20 C FLASH POINT 212 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26-28-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25 mg/m3 DOE Short Term Exposure Limit 75 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONENYLSUCCINIC ANHYDRIDE (2,1-) CAS # 28928974 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1364.5 mg/Kg INHALATION RISK INDEX 1.7 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Causes photosensitiveity. Exposure to light can which can vary from sunburnlike responses to edematous, vesiculated lesions, or bullae TARGET ORGAN(S) OR SYSTEM(S) SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Dizziness. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE Scientific literature indicates that the toxic effects of psoralens are linked to exposure to ultraviolet light(UVA), specifically sunlight. These are photosensitizing materials skin cancers in exposed areas, IARC Group 1. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: ong bases HAZARDOUS DECOMPOSITI REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONIDET P-40 CAS # 9036195 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 707.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Aspiration or inhalation may cause chemical pneumonitis. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .010000 mm Hg @ 20 C FLASH POINT 484 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials reactive with hydroxyl compounds, Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-38-41 Risk Statements: Harmful if swallowed. Irritating to skin. Risk of serious damage to eyes. S: 26-39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 50 mg/m3 DOE Ceiling Limit 350 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONOXYNOL (9-) CAS # 26027383 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 37/38 41 Risk Statements: Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .025 mg/m3 DOE Short Term Exposure Limit .075 mg/m3 DOE Ceiling Limit .6 mg/m3 Immediately Dangerous to Life and Health 60 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONYL ALDEHYDE CAS # 124196 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .210 mm Hg @ 20 C FLASH POINT 145.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 mg/m3 DOE Short Term Exposure Limit 6 mg/m3 DOE Ceiling Limit 40 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONYLPHENOL CAS # 11066492 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1310.0 mg/Kg INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: ZATION WILL NOT OCCUR The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONYLPHENOL (4-) CAS # 104405 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 1 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1620.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C N Indication of Danger: Corrosive. Dangerous for the environment. R: 22 34 50/53 Risk Statements: Harmful if swallowed. Causes burns. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 36/37/39 45 60 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NONYLPHENOL (N,4-) CAS # 84852153 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1300.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 22 Risk Statements: Causes burns. Harmful if swallowed. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 100 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NOPOL CAS # 35836738 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Inhalation: May be harmful if inhaled. Ingestion: Harmful if swallowed. Multiple Routes: Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 208.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORADRENALINE CAS # 51412 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.8 - LD50 75.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: TION OR DECOMPOSITION PRODUCTS THERMAL DECOMP The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORADRENALINE HYDROCHLORIDE CAS # 329566 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 132.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Heart. Smooth muscle. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause hypertension, headache, anxiety, palpitations, and respiratory difficulty. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Bases, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORADRENALINE HYDROCHLORIDE (DL-) CAS # 55276 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Heart. Smooth muscle. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause hypertension, headache, anxiety, palpitations, and respiratory difficulty. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Bases, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORBORNANEMETHANOL ENDO AND EXO (2-) CAS # 5240722 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1600.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 184 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORBORNENEMETHANOL (5,2-) CAS # 95125 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 1 2 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Vascular system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 188 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORBORNEOL (EXO-) CAS # 497370 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORETHINDRONE CAS # 68224 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.4 - LD50 19354.8 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 40 Risk Statements: Limited evidence of a carcinogenic effect. S: 22 36/37/39 45 Safety Statements: Do not breathe dust. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORFLOXACIN CAS # 70458967 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE May cause nausea, headache, dizziness, lightheadedness, crystalluria, gastrointestinal or neurological adverse effects. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORFLUDIAZEPAM CAS # 2886659 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 7258.1 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged or repeated exposure can lead to habituation or addiction. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 24/25 22 Safety Statements: Avoid contact with skin and eyes. Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORGESTREL CAS # 797648 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. May cause irritation. TARGET ORGAN(S) OR SYSTEM(S) Female reproductive system. Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid all contact. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 40 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. S: 22 36 Safety Statements: Do not breathe dust. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORLEUCINE (DL-) CAS # 616068 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.3 - LD50 24668.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORVALINE (DL-) CAS # 760781 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NORVALINE (L-) CAS # 6600404 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NUCLEAR FAST RED CAS # 6409774 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 36 26 Safety Statements: Wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. NUPERCAINE CAS # 85790 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . I J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 413.1 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Cardiovascular system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, an toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE Dibucaine is an extremely potent anesthetic agent. Symptoms of overexposure may include headache, nausea, vomiting, hypotension, and irregular heart rate. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 41 Risk Statements: Harmful if swallowed. Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. 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